PamcoPete shared an interactive spreadsheet for tire size, sprocket size and road speed some time ago that you may be able to find and download. I couldn't attach it to this reply, but playing with your info shows that a 17/36 sprocket combo and 16" rear would expect about 4650 rpm at 100kmh (61.6 mph). Similarly, 17/34 sprocket combo would show about 4400 rpm, and 17/32 combo would show about 4135. His spreadsheet uses mph, so these results are ratioed up from the 60 mph values to 61.6. So this also suggests that 5000 rpm at 100kmh is too high, even for the 17/36 combo. Make sure you're using motorcycle-specific oil - some of the automotive ones have friction modifiers that may promote some clutch slippage. Also ensure that your tach cable is well lubed.