Set the cam chain adjuster so it's flush with the pin when it moves out, not in. Yes, new chains are pretty tight but initially stretch out some quite quickly. You'll want to check, and probably need to re-set, the cam chain tension shortly after you get it running, in say 50 to 100 miles.
A properly done fresh rebuild, if everything's set right, usually starts right up, pretty much immediately. If all your other settings check out (valves, carbs), you may want to re-visit the timing. After all, that initial static timing you did is just a "ball park" setting. You might try moving it a little to the left and/or right of where it is now. That may get the timing closer and make it easier to start.
I'm pretty sure your Boyer uses a single coil with 2 plug wires. If so, that fires both those plug wires at the same time. There's no way to wire it up 180° out.
A properly done fresh rebuild, if everything's set right, usually starts right up, pretty much immediately. If all your other settings check out (valves, carbs), you may want to re-visit the timing. After all, that initial static timing you did is just a "ball park" setting. You might try moving it a little to the left and/or right of where it is now. That may get the timing closer and make it easier to start.
I'm pretty sure your Boyer uses a single coil with 2 plug wires. If so, that fires both those plug wires at the same time. There's no way to wire it up 180° out.