If you mean separate them from the angle bracket that holds them together as a bank, no, that's not necessary unless you're replacing the butterfly shaft seals. But I'd hold off on doing those for now. The ones in there may still be OK. They hold up better in the cooler, wetter northern climes as compared to like if you lived in Arizona where it's hot and dry.
To do a proper cleaning, you'll need compressed air to blow through the tiny orifices. Yes, scrub everything down inside and out to get it as clean as you can. I start with something mild like kerosene, only resorting to the carb cleaner for stubborn spots the mild stuff won't clean. If I put carb cleaner through the passageways, I flush them afterwards with mild stuff to get any carb cleaner residue out.
There's only one little o-ring in your carb set, on the needle jet. It may or may not need replacing. Check to see if the needle jet is tight in the carb body. If it's loose, it needs a new o-ring.