Yes, not to the engine. You want the gasket to come off with the boot any time you remove it, not stay stuck on the head. The manifold gasket (if it's the proper one) is quite thick, like a good 1/8" or so. The sealer isn't so much to seal it, it usually seals fine on it's own. It's so the gasket comes off with the manifold. Being that that is the reason for applying it, I don't coat the whole thing, just a thin (maybe 1/8" wide) bead around the gasket, a ring or circle of sealer.