I am fairly sure I have now by experiment and research understood the tire pressure question. It is that there exists more than one mechanism of pressure loss in the matter...more or less motorcycle tires, in this inquiry. It seems that there is permeability, in which case larger molecule gas would leak slower than air...
And! Solubility. Evidently some gases and the elastomeric material of inner-tubes and tires are mutually soluble, and a differential density results in condensation-evaporation through the "solute" (which it is) of the tubes and or tire. Solubility reigns.
CO2 acts as an organic solvent in the experiment...and it "leaks" (actually evaporates through) faster than air. The fact that it's a larger molecule seems to be a difficult thing to account for experimentally...but my science fair is finished... best gas tire is (probably so far) air. But I wonder about silicone oil films...